As I said, for cartesian printers it does not matter which offset your left extruder has. Only thing matters is difference between left and right extruder. When you switch extruders they should move so that the new active extruder is over the position of the now inactive extruder. Normally you set left one to 0,0,0 and right one then to 80 steps per mm * 32 mm=2560 steps, assuming 80 steps per mm for x axis. Configuration.h has mm, eeprom has steps as distance and you need to change in eeprom or you won't see a difference. It will always such that at homing position you can switch extruders without hitting the endstop. So you would have at least 32mm distance to the endstop after homing with first extruder active.