The weights can not be set from config file. Always initalized as 10 for all.
First weight for extr 1 and ext 2 correspond to T0 command, second to T1 and so on. Setting weights to 0 means does not use extruder.
Example
100 0 : T0 = 100% extruder 1
0 100 : T1 = 100% extruder 2
50 50 : T2 = 50% each
25 75 : T3 = 25% extruder 1 , 75% extruder 2
So you don't need M163 once they all have good meanings you switch with extruder selector.